casonline.blogg.se

The orbitron gallery of atomic orbital
The orbitron gallery of atomic orbital







the orbitron gallery of atomic orbital

So what you're seeing in the 2D graph is just the radial part of the wavefunction. The cross section is taken along a radial line, i.e. What they're plotting on the (2D) graph in those figures is a cross section of the wavefunction. My only clue for the answer to my question is that maybe angular nodes are not represented by x-intercepts. If one radial node causes the graph to cause the x-axis twice (on each side of nucleus, as in the case of the 2s orbital) then shouldnt there be 2 nodes * 2 intercepts/node = 4 intercepts just for the angular nodes? And then 2 more intercepts for the angular nodes? But the graph hits the x-axis at 5 (instead of 6) separate points which would imply 5 nodes but this isnt the case. The number of of radial nodes is 2 (from equation n-l-1) and the number of angular nodes is l=2.

the orbitron gallery of atomic orbital

Now consider the graph of Ψ for a 5d orbital. The graph intersects at two points, but these two intercepts represent the same spherical node. Take for example, the graph of Ψ for a 2s orbital as seen on the left here: I am having a hard time understanding the nodes on the graphs of Ψ for atomic orbitals.









The orbitron gallery of atomic orbital